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It is typical for chemistry texts to write the first law as U=Q+W.It is the same law,of course - the thermodynamic expression of the conservation of energy principle.It is just that W is defined as the work done on the system instead of work done by the system.In the context of physics,the common scenario is one of adding heat to a File Size 197KBPage Count 15US Department of EducationUS Department of EducationEnergy,Enthalpy,and the First Law of ThermodynamicsWhat would happen if we created a set of conditions under which no work is done by the system on its surroundings,or vice versa,during a chemical reaction? Under these conditions,the heat given off or absorbed by the reaction would be equal to the change in the internal energy of the system.E sys = q (if and only if w = 0)
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